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2 edition of Gas phase hydrogen permeation in palladium-25%Ag. found in the catalog.

Gas phase hydrogen permeation in palladium-25%Ag.

Rosita Mousavinejad

Gas phase hydrogen permeation in palladium-25%Ag.

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Published .
Written in English


About the Edition

The results have shown an unexpected through-thickness texture gradient in the as-received Pd alloy. With the exception of a minor stabilization effect for one specific texture component, gas phase hydrogen permeation for up to 48 hours at 350°C has no significant effect on the crystal orientation with respect to the membrane surface.A hydrogen permeation facility based on an ultra high vacuum system was assembled with the ultimate goal to investigate gas phase hydrogen permeation through various metal foils. The system was designed with a membrane holder that does not require welding or brazing of the membrane to the supporting flange.Hydrogen permeation experiments were carried out on cold rolled Pd-25% Ag foils with a thickness of 127 mum at 350°C for various time intervals and a constant flow rate of hydrogen. The effect of hydrogen permeation on the microstructure of the membrane material was studied by X-ray diffraction.

The Physical Object
Pagination63 leaves.
Number of Pages63
ID Numbers
Open LibraryOL20238515M
ISBN 100494022582

Avoid α β phase transition Improve mechanical property Improve hydrogen permeability Increase resistance to the surface poisoning Identical specimens of palladium (left) and palladium thermal cycles in hydrogen G.J. Grashoff et al, Platinum Metals Rev., 27 (4), , Alloying 5. Gas phase titration as described in reference 6, section Nitrogen dioxide: 1. Gas phase titration as described in reference 6 2. Permeation device, similar to system described in reference 6: 1. Use an FRM NO 2 analyzer calibrated with a gravimetrically calibrated permeation device. 2. Also, hydrogen can be an "acceptor" of an electron to complete its shell (see lithium hydride). V , 6 February (UTC) Regarding Hydrogen as a Alloying substance. The subsection of the article, "hydrogen permeation of metals" could use some extra supporting evidence or argument. I have here an argument that may be OR. 4 H2 permeation through Pd films Introduction limiting step for hydrogen permeation. However, if the Pd film thickness is very small, a relation between H2 pressure in the gas phase and the H dissolved in the Pd bulk needs to be used. At very low H2 pressures, the.


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Gas phase hydrogen permeation in palladium-25%Ag. by Rosita Mousavinejad Download PDF EPUB FB2

Nomenclature B 0. viscous permeability of the support matrix, m 2. b i. Langmuir affinity constant of species i, Pa −1. c i. concentration of species i, mol m −3. diameter, m. molecular gas-phase diffusivity, m 2 s −1. D H. atomic hydrogen diffusivity in palladium, m 2 s −1.

Ð H 2, M e. effective binary Knudsen diffusivity for hydrogen with respect to the support matrix, m s −1Cited by: Chemical and Petroleum Engineering Dept., University of Pittsburgh, Pittsburgh, PA Search for more papers by this authorCited by: 6.

temperature, MH2 [kg/mol] the molar mass of hydrogen, µH2 [kg/m.s] the gas viscosity, and finally PH2,per and PH2,ret [Pa] are the hydrogen partial pressure in the permeate and in the retentate sides. The total permeation flow is the sum of 3 different contribution: the atomic flow through palladium and the flow through membrane defects via Cited by: 6.

In this work, the hydrogen and deuterium transport parameters such as permeability, diffusivity, and solubility in a Pd pct Ag alloy are studied, using a permeation gas phase. Permeation through membranes, Gas phase hydrogen permeation in palladium-25%Ag. book those made of palladium alloys such as Pd–Ag, is also mentioned and sometimes proposed as a potential process for the separation of Gas phase hydrogen permeation in palladium-25%Ag.

book isotopes as required in future fusion plants.Two primary techniques can be distinguished for this process: large total pressure differences (A) or only partial pressure differences across the permeation Cited Gas phase hydrogen permeation in palladium-25%Ag. book A high purity hydrogen gas stream is crucial to the performance of fuel cells since certain species poison the catalysts even at very low concentrations In the case of CO, a strong adsorbing species, less than 10 ppm is typically required The application of a highly selective palladium-based membrane may be utilized to purify the gas, and is currently the most advanced Cited by: Thermal balance experiments in hydrogen at pressures from 1– torr up to ° C show rapid absorption from ° C for Y 5 Si 3 producing an α-phase x = 0−, a β phase x = −, and an amorphous γ-phase x = ≧ Abstract: Gas permeation of hydrogen (H 2) and nitrogen (N 2) were obtained from 30 and nm pore diameter tubular commercial alumina ceramic membranes at to bar and K.

Flow rates of up to and l/min were obtained for H 2 and N 2 respectively. The ratio of H 2 /N 2 flow rates were used to calculate H 2 /N 2 selectivity. The experimental H 2 /N 2.

The quantity that characterizes the gas permeation Gas phase hydrogen permeation in palladium-25%Ag. book of a membrane, permeance Q (or P/l), is expressed in the units cm 3 (STP)/(cm 2 s cm Hg) or m 3 (STP)/m 2 h atm or mol/m 2 s Pa. Permeance is also often expressed in gas permeation units (GPU), where 1 GPU = 10 − 6 cm 3 (STP)/(cm 2 s cm Hg).

The hydrogen permeation reduction factor (PRF) evaluated in gas phase is at K and at K, and in liquid PbLi phase is Gas phase hydrogen permeation in palladium-25%Ag.

book. transfer coefficient at the boundary between gas phase and permeation membrane. In addition, tritium permeation behavior through Pd-Ag allo y or stainless steels was numerically estimated for the case of H. 2-T. binary component system. THEORY. The permeation behavior of hydrogen isotopes Gas phase hydrogen permeation in palladium-25%Ag.

book the metal membrane consists of following File Size: 89KB. Permeation through a membrane 4. Chemical conversion to another compound 5. Condensation • Absorption: It refers to the transfer of a component of a gas phase to a liquid phase File Size: 1MB. Gas phase hydrogen permeation in alpha titanium and carbon steels.

Washington, D.C.: National Aeronautics and Space Administration, Scientific and Technical Information Office ; [Springfield, Va.: For sale by the National Technical Information Service], (OCoLC) Material Type: Government publication, National government publication.

Nelson, H.G., & Stein, J.E. Gas-phase hydrogen permeation through alpha iron, steel, and stainless steel from less than /sup 0/C to near /sup 0/C. United States. United States. Copy to clipboard. This massively updated and expanded fifth edition is the most complete, authoritative engineering treatment of the dehydration and gas purification processes used in industry today.

Of great value to design and operations engineers, it gives practical process and equipment design descriptions, basic data, plant performance results, and other detailed information on gas purification /5(4).

Hydrogen gas driven permeation through fine-grain graphite MPG-8 has been investigated in the range of thickness from to mm and pressures from 10−2 to 1Pa. Abstract. A precise hydrogen permeation experiment for beryllium was conducted at a temperature ranging from to K under hydrogen gas pressure of 10{sup 1} to 10{sup 3} Pa.

Diffusion coefficient and permeation coefficient were determined from the steady state permeation and time transient permeation independently. Despite being only one-atom thick, defect-free graphene is considered to be completely impermeable to all gases and liquids 1,2,3,4,5,6,7,8,9,This conclusion is based on theory 3,4,5,6,7,8 and Cited by: 1.

The basic technologies and all significant advances in the following areas are thoroughly described: sulfur dioxide removal and recovery processes, processes for converting hydrogen sulfide to sulfur, liquid phase oxidation processes for hydrogen sulfide removal, the absorption of water vapor by dehydrating solutions, gas dehydration and /5(6).

Membranes for gas separation are pro-duced in the form of hollow fibers by a phase-inversion process. Gas separation membranes work on the principle of selective permeation through a membrane surface.

The driving force for gas per-meation through the membrane is the difference between the partial pressures of the gas on the retentate side (theFile Size: KB. The process begins when pressurized feed gas is sent to the coalescing filter to remove contaminants and protect the membrane fiber from liquid aerosols and particulates.

Feed gas is then preheated before entering the membranes. These membranes produce the hydrogen-rich permeate and hydrogen-lean residue. The. Oxygen and hydrogen permeability through Nafion® membrane and recast Nafion film has been studied by means of gas chromatography at different values of temperature and gas relative humidity.

Water uptake from the vapour phase by Nafion® membrane and recast film has been investigated. It has been shown that oxygen and hydrogen permeability Cited by: Hydrogen peroxide and organic hydroperoxide in the troposphere: a review. Atmospheric Environment34 (21), DOI: /S(99)X.

Jörg Meyer, Uwe Karst. Workplace monitoring of gas phase hydrogen peroxide by means of Cited by: Purchase Gas Purification - 5th Edition. Print Book & E-Book. ISBNIn physics and engineering, permeation (also called imbuing) is the penetration of a permeate (such as a liquid, gas, or vapor) through a is directly related to the concentration gradient of the permeate, a material's intrinsic permeability, and the materials' mass tion is modeled by equations such as Fick's laws of diffusion, and can be measured using tools.

hydrogen absorption by palladium from the gas phase (I,43) and have also produced interest (39,54,64) as to the extents to which total hydrogen overpotentials may contain contribu- tions associated with high hydrogen chemical potentials at the initial discharge sites.

Allied interest also has continued in the general area. In our previous work (McLeod et al., Proceedings of ASME Summer Heat Transfer Conference, San Francisco, CA) a steady-state model was developed which divides the hydrogen permeation sequence into seven distinct regimes: gas phase mass transport to the surface, adsorption onto the surface, transition into the bulk material, solid-phase Author: Logan S.

McLeod, Levent F. Degertekin, Andrei G. Fedorov. @article{osti_, title = {Permeation of hydrogen in hastelloy C alloy at high temperature}, author = {Zhang, D.

and Liu, W. and Qian, Y. and Que, J.}, abstractNote = {Tritium is generated by the interaction of neutrons with the lithium and beryllium in the molten salt reactors (MSRs), which use FLiBe as one of solvents of fluoride fuel. conducted to investigate the effect on hydrogen permeation rate.

A Pd-Ag membrane reactor phase to β phase which caused lattice expansion and crystal distortion which caused defects Figure Long term permeability of pure hydrogen gas on Pd-Ag at oC and 4 bars.

The effects of poisoning by nitrogen and ammonia in the hydrogen gas on hydrogen permeation through Pd-rich Pd-Y(Gd)-Ag and Pd-Y-In(Sn, Pb) alloy series have been investigated using mixture gases. To this end, we are developing micromachined Pd/Ag alloy membranes for in-situ hydrogen separation suitable for integration with catalytic fuel reforming microreactors.

In this work, we report an analysis of mass transport and kinetics of hydrogen permeation through a non-porous palladium membrane for the case of the sub-micron membrane by: 3. Pd-7 wt% Y alloy has the highest hydrogen permeabil-ity and strength but the lowest plasticity of the alloys studied.

Effects of Temperature Palladium alloys dissolve hydrogen to concentrations of around – at% H directly from the gas phase. Stresses resulting from the increase in alloy volume upon hydrogen dissolution are the principal File Size: KB.

Hence, the optimization of the hydrogen permeation kinetics first requires to separately measure surface and bulk rate constants associated to these individual steps. Gas-phase impedance spectroscopy (also called pneumato-chemical impedance spectroscopy or PIS) is a rather simple but nonetheless powerful technique that can be used for that purpose.

While polymeric membranes are economical and technologically useful, they are bounded by their performance, known as the Robeson limit (permeability must be sacrificed for selectivity and vice versa). This limit affects polymeric membrane use for CO 2 separation from flue gas streams, since mass transport becomes limiting and CO 2 separation becomes very expensive due to.

Considerations of various aspects of surface heterogeneity have received increasing attention in regard to studies of the kinetics of hydrogen absorption by palladium from the gas phase (1, 43) and have also produced interest (39, 54,64) as to the extents to which total hydrogen overpotentials may contain contributions associated with high.

He has been awarded more than 25 patents in gas purification and other chemical engineering fields. Richard Nielsen is a Director of Process Engineering at Fluor Daniel's Irvine, California office.

His 20 years with Fluor Daniel include work in gas treating, gas processing, and refining/5(7). Then, hydrogen absorption is discussed and shown to be decisively determined by the enthalpy of solution, in particular by its sign which specifies whether absorption is exothermic or endothermic.

The formation of high-pressure hydrogen gas bubbles in a metal, which can lead to blistering, is by: A new class of gas separation membranes has been developed which consist of thin, nanoporous (pore diameters of {angstrom}) layers of adsorbent carbon supported on a macroporous support Gas separation is accomplished by selective adsorption, and selective surface flow of the more strongly adsorbed component of the feed gas mixture.

This massively updated and expanded fifth edition is the most complete, authoritative engineering treatment of the dehydration and gas purification processes used in industry today.

Of great value to design and operations engineers, it gives practical process and equipment design descriptions, basic data, plant performance results, and other detailed information on gas purification. diffusion in an through solids. The Behaviour of Hydrogen Isotopes in Diffusion.

metal method migration mobility molecular molecules nitrogen observed obtained occurs oxide oxygen palladium permeability constants permeation rate permeation velocity phase Phys plane plate Poiseuille flow polymers pore potassium pressure Proc pyrex 5/5(1).

After dehydration the membranes were characterized pdf single-gas H2, N2 and CO2 permeation at K and exhibited the H2/N2 and Pdf permselectivity of ∼3 and ∼4, respectively. Synthesis and gas permeation properties of sodalite membranes.

Snyder, Mark A. ; Vlachos, Dionisios G. / Synthesis and gas permeation properties of Author: Zhenkun Zheng, Vadim Guliants, Jerry Lin, Mark A. Snyder, Dionisios G. Vlachos.Abstract. Hydrogen is inevitably formed at corroding metal surfaces download pdf oxygen free environments such wet sour gas or sour crude oil.

Part of the hydrogen becomes absorbed into the metal substrate and once into the steel the hydrogen may recombine at phase boundaries and non metallic inclusions to cause blistering or collect at sites of high stresses where it interferes with .Ebook most common method of hydrogen storage is compression of the gas ebook at high pressure (> bars or psi).

Compressed hydrogen in hydrogen tanks at bar (5, psi) and bar (10, psi) is used in hydrogen vehicles. There are two approaches to increase the gravimetric and volumetric storage capacities of compressed gas by: